| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | H.E. George B. Rusimbi | Ambassador | 1970 -1974 |
| 2 | H.E. George M. Nhigula | Ambassador | 1974 - 1978 |
| 3 | H.E. Ahmed H. Diria | Ambassador | 1978 - 1983 |
| 4 | H.E. Raphael H. Lukindo | Ambassador | 1983 - 1988 |
| 5 | H.E. Ali S. Mchumo | Ambassador | 1988 - 1991 |
| 6 | H.E. Pius Y. Ng'wandu | Ambassador | 1991 - 1993 |
| 7 | H.E. Isaya B. Chialo | Ambassador | 1993 - 1999 |
| 8 | H.E. Elly E. E. Mtango | Ambassador | 2000 - 2009 |
| 9 | H.E. Salome T. Sijaona | Ambassador | 2010 - 2015 |
| 10 | H.E. Dr. Batilda S. Burian | Ambassador | 2015 - 2016 |
| 11 | H.E. Mathias M. Chikawe | Ambassador | 2016 - 2019 |
| 12 | H.E. Hussein A. Kattanga | Ambassador | 2020 - 2021 |
| 13 | H.E. Baraka Haran Luvanda | Ambassador | 2021 - 2025 |
