| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | H.E. Mathias Meinrad Chikawe | Ambassador | 2016 - 2019 |
| 2 | H.E. Dr. Batilda S. Burian | Ambassador | 2015 - 2016 |
| 3 | H.E. Salome T. Sijaona | Ambassador | 2010 - 2015 |
| 4 | H.E. Elly E. Mtango | Ambassador | 2000 - 2009 |
| 5 | H.E. Ahmed Hassan Diria | Ambassador | 1979 - 1984 |
| 6 | H.E. George Maige Nhigula | Ambassador | 1974 - 1978 |
